You can use an unlimited number of ships to protect a trade node. This can indeed be a good strategy if it is one of the major New World nodes (Chesapeake Bay / Carribean).Or you can place all your ships on one route to gain maximal trade power?
But remember that trade power from ships does only apply to that node alone, so there is no reason to pile more ship on it if you already have 95% of the total trade power there.