yes it was just temporary, once the war is over you demobilize and the POPs go back to their original categories.
Mobilizing makes them soldier units
Except it they didn't, did they? I don't remember it ever being fixed, they always turned back into farmers/laborers.
Anyway, I'm hoping mobilising in V2 won't convert entire pops, just shave 3k segments off them to form into brigades. So if you have, say, a 30 brigade mobilisation pool it'll take 3000 men from 30 different large pops rather than converting one 90k pop.