Most people interested in the history of Eastern Europe probably know (or at least they should) that such a union has been considered several times in actual history. Several attempts/suggestions were made, including Ivan the Terrible being pretty close to being elected the monarch of the PLC, Polish prince Vladislav actually having been elected the tsar of Russia (later expelled though), and several others.
http://en.wikipedia.org/wiki/Polish-...e_Commonwealth
This should obviously be
extremely difficult to achieve, due to lots of underlying contradictions in religion, political systems et cetera. All these factors actually prevented it in the real history.